Nitrogen dynamics model for a pilot field-scale novel dewatered alum sludge cake-based constructed wetland system.

A model simulating the effluent nitrogen (N) concentration of treated animal farm wastewater in a pilot on-site constructed wetland (CW) system, using dewatered alum sludge cake (DASC) as wetland substrate, is presented. The N-model was developed based on the Structural Thinking Experiential Learning Laboratory with Animation software and is considering organic nitrogen, ammonia nitrogen (NH3) and nitrate nitrogen (NO3-N) as the major forms of nitrogen involved in the transformation chains. Ammonification (AMM), ammonia volatilization, nitrification (NIT), denitrification, plant uptake, plant decaying and uptake of inorganic nitrogen by algae and bacteria were considered in this model. pH, dissolved oxygen, temperature, precipitation, solar radiation and nitrogen concentrations were considered as forcing functions in the model. The model was calibrated by observed data with a reasonable agreement prior to its applications. The simulated effluent detritus nitrogen, NH4-N, NO3-N and TN had a considerably good agreement with the observed results. The mass balance analysis shows that NIT accounts for 65.60%, adsorption (ad) (11.90%), AMM (8.90%) followed by NH4-N (Plants) (5.90%) and NO3-N (Plants) (4.40%). The TN removal was found 52% of the total influent TN in the CW. This study suggested an improved overall performance of a DASC-based CW and efficient N removal from wastewater.

Comprehensive analysis of step-feeding strategy to enhance biological nitrogen removal in alum sludge-based tidal flow constructed wetlands.

Step-feeding strategies have been extensively studied and comprehensively analyzed in this study for a four-stage alum sludge-based tidal flow constructed wetlands (AlS-TFCWs) system. Enhanced total nitrogen removal of 83% is achieved under high nitrogen loading rate of 19.1 g N/m(2)d. The key issues towards the success of a significant nitrogen removal in step-feeding TFCWs are the bed resting time (which provides better aeration for nitrification) and up flow stage/delayed input of side stream(s) (which ensure favorable environment for better denitrification). Simultaneous nitrification and denitrification (SND) was found effective in the 1st stage of the system and SND via nitrite is the main nitrogen conversion mechanism. The optimal influent distribution fraction for step-feeding purpose can be estimated from a theoretical basis, which is a function of the influent BCOD/TKN ratio. Therefore the influent distribution fraction should be adjusted according to the variety of influent characteristics, rather than a fixed value.

Process-based modelling of phosphorus removal in a novel constructed wetland system using dewatered alum-sludge as substrate.

A process-based model that can evaluate the transport and the fate of phosphorus (P) in agricultural wastewater was developed for a novel 4-stage dewatered alum sludge cakes (DASC) based constructed wetlands (CWs) system using STELLA software (version 9.1.4). The model considered adsorption, plant and microbial uptakes as the major forms of P involved in the transformation chains. The results were obtained by experimental procedure through laboratory measurement, from literature and/or calibration. The observed effluent P concentration in the CWs ranged from 3.62 to 8.50 mg/L (stage 1), 2.00 to 4.45 mg/L (stage 2), 1.39 to 3.76 mg/L (stage 3) and 0.52 to 2.36 mg/L (stage 4), whereas the simulated values ranged from 2.12 to 10.99 mg/L (stage 1), 1.32 to 5.65 mg/L (stage 2), 0.84 to 3.64 mg/L (stage 3) and 0.53 to 2.25 mg/L (stage 4), respectively. The simulated and observed values of P removal in the CWs system were in good agreement. A mass balance analysis was performed for all the major processes which resulted in a major pathway of P removal through adsorption (64-75%, 58-66%, 57-63% and 49-58%) followed by plant uptake (7-11%, 8-14%, 14-17% and 9-19%) and microbial uptake (3-7%, 3-5%, 9-12% and 7-12%) for stage 1, stage 2, stage 3 and stage 4, respectively. Thus the mathematical model developed in this study could be used to explain the removal processes and simulate the fate of P in the DASC-based CWS system.

STELLA software as a tool for modelling phosphorus removal in a constructed wetland employing dewatered alum sludge as main substrate.

A dynamic simulation model was developed for the removal of soluble reactive phosphorus (SRP) from the vertical flow constructed wetlands (VFCW) using a dynamic software program called STELLA (structural thinking, experiential learning laboratory with animation) 9.1.3 to aid in simulating the environmental nature and succession of relationship between interdependent components and processes in the VFCW system. In particular, the VFCW employed dewatered alum sludge as its main substrate to enhance phosphorus (P) immobilization. Although computer modelling of P in treatment wetland has been well studied especially in recent years, there is still a need to develop simple and realistic models that can be used for investigating the dynamics of SRP in VFCWs. The state variables included in the model are dissolved phosphorus (DISP), plant phosphorus (PLAP), detritus phosphorus (DETP), plant biomass (PLBI) and adsorbed phosphorus (ADSP). The major P transformation processes considered in this study were adsorption, plant and microbial uptake and decomposition. The forcing functions which were considered in the model are temperature, radiation, volume of wastewater, P concentration, contact time, flow rate and the adsorbent (i.e., alum sludge). The model results revealed that up to 72% of the SRP can be removed through adsorption process whereas the uptake by plants is about 20% and the remaining processes such as microbial P utilization and decomposition, accounted for 7% SRP removal based on the mass balance calculations. The results obtained indicate that the model can be used to simulate outflow SRP concentration, and it can also be used to estimate the amount of P removed by individual processes in the VFCW using alum-sludge as a substrate.

Effects of livestock wastewater variety and disinfectants on the performance of constructed wetlands in organic matters and nitrogen removal.

BACKGROUND, AIM AND SCOPE: Treatment performance of constructed wetlands (CWs) is largely dependent on the characteristics of the wastewater. Although livestock wastewater is readily biodegradable in general, its variety in biodegradability can still be significant in practice. In addition, it is a common practice to periodically use disinfectants in livestock activities for health concerns. Obviously, the residual of the disinfectants in livestock wastewater may have serious inhibitory effect on the microbial activities during wastewater treatment. Thus, the main objective of this study was to examine the variety of livestock wastewater in biodegradability and its effect on the performance of a pilot scale tidal flow CWs (TFCWs) in organic matter and nitrogen removal. Furthermore, investigation of the potential inhibition of the chosen disinfectants on organic matter biodegradation and nitrification was another aim of this study. MATERIALS AND METHODS: The TFCWs system consisted of four-stage downflow reed beds with a hydraulic loading rate of 0.29 m(3)/m(2)·per day. Long-term stored livestock wastewater and fresh livestock wastewater were used, respectively, as feed to the system in different periods. Meanwhile, batch aeration tests were carried out to investigate the difference in biodegradation of the two types of wastewaters. Inhibitions of two types of disinfectants, namely UNIPRED and HYPROCLOR ED, on microbial activities were investigated in laboratory batch tests, with dosage of from 0.05% to 0.5%. RESULTS: With fresh livestock wastewater, removal efficiencies of up to 93% and 94% could be achieved with average of 73% and 64% for chemical oxygen demand (COD) and TN, respectively. The performance deteriorated when the system was fed with long-term stored wastewater. In the batch tests, the long-time stored wastewater was characterized as non-biodegradable or at least very slowly biodegradable, while the fresh wastewater was readily biodegradable. UNIPRED showed very strong inhibition on both heterotrophic organisms and nitrifiers. Tested inhibition started from content of 0.05%, which is 1/10 of the recommended usage rate. Inhibitory effect of HYPROCLOR ED on COD degradation started from 0.1% and complete inhibition occurred from content of 0.3%, while significant inhibition on nitrification started from 0.1%. CONCLUSIONS: Livestock wastewater could vary significantly in biodegradability and it may turn to be non-biodegradable after a long-term storage. The variety of the livestock wastewater has a decisive influence on the performance of the CWs system, especially in TN elimination. In addition, the application of disinfectants UNIPRED and HYPROCLOR ED may cause serious inhibition on microbial activities and subsequent system failure.

On the fit of statistical and the k-C* models to projecting treatment performance in a constructed wetland system.

The objective of this study was to assess the suitability of statistical and the k-C* models to projecting treatment performance of constructed wetlands by applying the models to predict the final effluent concentrations of a pilot field-scale constructed wetlands system (CWs) treating animal farm wastewater. The CWs achieved removal rates (in g/m(2).d) ranging from 7.1-149.8 for BOD(5), 49.8-253.8 for COD and 7.1-47.0 for NH(4)-N. Generally, it was found that the statistical models developed from multiple regression analyses (MRA) were stronger in predicting final effluent concentrations than the k-C* model. However, both models were inadequate in predicting the final effluent concentrations of NO(3)-N. The first-order area-based removal rate constants (k, m/yr) determined from the experimental data were 200.5 for BOD(5), 80.1 for TP and 173.8 for NH(4)-N and these indicate a high rate of pollutant removal within the CWs.

Performance evaluation and prediction for a pilot two-stage on-site constructed wetland system employing dewatered alum sludge as main substrate.

Dewatered alum sludge, a widely generated by-product of drinking water treatment plants using aluminium salts as coagulants was used as main substrate in a pilot on-site constructed wetland system treating agricultural wastewater for 11 months. Treatment performance was evaluated and spreadsheet analysis was used to establish correlations between water quality variables. Results showed that removal rates (in g/m(2)d) of 4.6-249.2 for 5 day biochemical oxygen demand (BOD(5)), 35.6-502.0 for chemical oxygen demand (COD), 2.5-14.3 for total phosphorus (TP) and 2.7-14.6 for phosphate (PO(4)P) were achieved. Multiple regression analysis showed that effluent BOD(5) and COD can be predicted to a reasonable accuracy (R(2)=0.665 and 0.588, respectively) by using input variables which can be easily monitored in real time as sole predictor variables. This could provide a rapid and cheap alternative to such laborious and time consuming analyses and also serve as management tools for day-to-day process control.

A review on numerous modeling approaches for effective, economical and ecological treatment wetlands.

Constructed wetlands (CWs) for wastewater treatment have evolved substantially over the last decades and have been recognized as an effective means of "green technology" for wastewater treatment. This paper reviews the numerous modeling approaches ranging from simple first-order models to more complex dynamic models of treatment behaviour in CWs. The main objective of the modeling work is to better understand the process in CWs and optimize design criteria. A brief study in this review discusses the efforts taken to describe the process-based model for the efficient removal of pollutants in CWs. Obtaining better insights is essential to understand the hydraulic and biochemical processes in CWs. Currently, employed modeling approaches can be seen in two categories, i.e. "black-box models" and "process-based models". It is evident that future development in wetland technology will depend on improved scientific knowledge of internal treatment mechanisms.